Procedura wizualizacji śladów daktyloskopijnych na papierze zwykłym i termicznym z wykorzystaniem elektronowej energii wzbudzenia agregatów 1,8-diazafluoren-9-onu w polimerze poliwinylopirolidonu
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RIS BIB ENDNOTEData publikacji: 10.10.2024
Problems of Forensic Sciences (Z Zagadnień Nauk Sądowych), 2024, 138, s. 111 - 122
https://doi.org/10.4467/12307483PFS.24.007.20180Autorzy
A procedure for the visualization of fingerprint traces on standard and thermal paper using the electron excitation energy of 1,8-diazafluoren-9-one aggregates in a polyvinylpyrrolidone polymer
The scope of this study is a new procedure for visualizing dactyloscopic traces on an absorbent surface using a solution based on aggregates of 1,8-diazafluoren-9-one (DFO) in a polyvinylpyrrolidone polymer (PVP). An absorbent surface is defined as a plain or thermal paper, which is considered to be a difficult surface due to its varying chemical composition. In the case of the thermal paper surface, the procedure can be further improved by the addition of Au/Ag nanoparticles, which cause an enhancement of the fluorescence phenomenon from the surface of the fingerprint. The procedure requires the use of forensic illuminators and filters to reveal traces at the crime scene. Regarding the visualization of fingerprint prints in the forensic laboratory, the use of a stereo fluorescence microscope provides higher-resolution images when analyzing single patterns in the form of minutiae. The presented procedure is competitive with known, highly toxic current methods for revealing dactyloscopic traces using the DFO molecule. It also represents a key contribution to the development of methods for visualizing traces on thermal paper using fluorescent dyes and suitable control of their spectroscopic properties.
1. Alem L, Valentin ESB, Cunha MA, Santos OCL, Nogueira TLS, Carvalho EF, et al. Efficiency of DNA recovery from fingerprints enhanced with black and magnetic powders. Forensic Sci Int Genet Suppl Ser. 2017 Dec 1;6:e490-e491.
2. Nontiapirom K, Bunakkharasawat W, Sojikul P, Panvisavas N. Assessment and prevention of forensic DNA contamination in DNA profiling from latent fingerprint. Forensic Sci Int Genet Suppl Ser. 2019 Dec 1;7(1):546-548.
3. Raymond JJ, Roux CC, Walsh SJ. Friction ridge skin: interaction between fingerprint detection and DNA/biological material. In: Jamieson A, Moenssens A, editors. Wiley encyclopedia of forensic science. Wiley; 2009. p. 1-7.
4. Grigg R, Mongkolaussavaratana T, Pounds CA, Sivagnanam S. 1, 8-diazafluorenone and related compounds. A New reagent for the detection of α-amino acids and latent fingerprints. Tetrahedron Letters. 1990;31(49), 7215-7218.
5. Hamilton PB. Amino-acids on hands. Nature. 1965;205(4968):284-285.
6. Wilkinson D. Study of the reaction mechanism of 1,8-diazafluoren-9-one with the amino acid, L-alanine. Forensic Sci Int. 1999;109(2000):87-103.
7. Friesen JB. Forensic chemistry: the revelation of latent fingerprints. J Chem Educ. 2015 Mar 10;92(3):497-504.
8. D’Elia V, Materazzi S, Iuliano G, Niola L. Evaluation and comparison of 1,2-indanedione and 1,8-diazafluoren-9-one solutions for the enhancement of latent fingerprints on porous surfaces. Forensic Sci Int. 2015 Sep 1;254:205-214.
9. Stojkovikj S, Oklevski S, Jasuja OP, Najdoski M. Visualization of latent fingermarks on thermal paper: a new method based on nitrogen dioxide treatment. Forensic Chemistry. 2020;17;100196.
10. Schwarz L, Klenke I. Improvement in latent fingerprint detection on thermal paper using a one-step ninhydrin treatment with polyvinylpyrrolidones (PVP). J Forensic Sci. 2010 Jul;55(4):1076-1079.
11. Luo YP, Zhao Y Bin, Liu S. Evaluation of DFO/PVP and its application to latent fingermarks development on thermal paper. Forensic Sci Int. 2013;229(1-3):75-79.
12. Szczepański T, Więckiewicz U, Klemczak K, Chyczewska A. A study of fluorescence emission intensity of reaction products between selected amino acids and DFO, 1,2-indanedione and 1,2-indanedione – zinc chloride. Issues of Forensic Sciences. 2014;285(3);1-5.
13. Trozzi TA, Schwartz RL, Leighton LD, Schehl SA, Trozzi YE, Wade C, editors. Processing guide for developing latent prints. United States Department of Justice. Federal Bureau of Investigation, Laboratory Division; 2001.
14. Conn C, Ramsay G, Roux C, Lennard C. The effect of metal salt treatment on the photoluminescence of DFO-treated fingerprints. Forensic Sci Int. 2000;116(2001):117-123.
15. Lewkowicz A. Patent Pending P.443382 (Polish Patent Office): Method of visualising dactyloscopic traces on absorbent surfaces and final solution for visualising dactyloscopic traces on absorbent surfaces (Sposób wizualizacji śladów daktyloskopijnych na podłożu chłonnym oraz roztwór końcowy do wizualizacji śladów daktyloskopijnych na podłożu chłonnym).
16. Zygadło P, Lewkowicz A. Structural-spectroscopic analysis of DFO/PVA films as potential materials used in revealing fingerprints on non-porous surfaces. Issues of Forensic Sciences. 2021;312(2):68-80.
17. Lewkowicz A, Kantor M, Zalewski W, Bojarski P, Mońka M. Spectroscopic evidence of fluorescence by 1,8‐diazafluoren‐9‐one aggregates – a prospective new ultrasensitive method for fingerprint trace detection. J Forensic Sci. 2022 March 28;67(4):1468-1475.
18. Lewkowicz A, Bogdanowicz R, Bojarski P, Pierpaoli M, Gryczyński I, Synak A, et al. The luminescence of 1,8-diazafluoren-9-one/titanium dioxide composite thin films for optical application. Materials. 2020 Jul 6;13(13):3014-3025.
19. Siddhanta S, Wróbel MS, Barman I. Integration of protein tethering in a rapid and la-bel-free SERS screening platform for drugs of abuse. Chemical Communications. 2016;52(58):9016-9019.
20. Lewkowicz A, Walczewska-Szewc K, Czarnomska M, Gruszczyńska E, Pierpaoli M, Bogdanowicz R, Gryczyński Z. Molecular design using selected concentration effects in optically activated fluorescent matrices. Int J Mol Sci. 2024;25,4804-4817.
Informacje: Problems of Forensic Sciences (Z Zagadnień Nauk Sądowych), 2024, 138, s. 111 - 122
Typ artykułu: Oryginalny artykuł naukowy
Tytuły:
Uniwersytet Gdański
Polska
Uniwersytet Gdański
Polska
Uniwersytet Gdański
Polska
Politechnika Gdańska
Polska
Politechnika Gdańska
Polska
Uniwersytet Gdański
Polska
Uniwersytet Gdański
Polska
Publikacja: 10.10.2024
Otrzymano: 19.02.2024
Zaakceptowano: 17.06.2024
Status artykułu: Otwarte
Licencja: CC BY-NC-ND
Finansowanie artykułu:
Udział procentowy autorów:
Korekty artykułu:
-Języki publikacji:
Angielski, Polski